The chemistry of five-membered and six-membered conjugated cyclic ligands complexes belongs to the most important classes of organometallic compounds. The determination of the precise
nature of the me...
The title compound, [PdBr(C3H5)(C9H8N2)], was synthesized by the reaction of the allylpalladium(II) bromide dimer and 1-phenyl-1H-imidazole. The Pd atom is coordinated by one allyl
group [inη3 mo...
The monoclinic title complex, [PtI2(C8H12)], characterized by a twisted cyclooctadiene ring, is similar to its Cl and Br orthorhombic homologues. The observed Pt—I bond
distances of 2.6094 ...
Both complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C14H20N2)]PF6, are almost parallel [dihedral angle between planes = 5.34 (13)°].
Among the C atoms of the co...
The title compound, [Ru(η5-C5H5){η6-C6H2(CH3)3NH2}]PF6, contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of
the amino group due to re...
The title compound,
[Ru(C5H5)(C3H5N)(C18H15P)2]CF3SO3, forms yellow crystals with a
distinctly hemimorphic habit. It contains a half-sandwich complex
of ruthenium with a three-legged piano-stool geome...
At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C15H20O4)]PF6, are almost parallel [dihedral angle between planes =
4.10 (14)°]. Am...
At 296 (2) K, both complexed rings in the iron(II) complex cation of the title salt, [Fe(C5H5)(C16H10O2)]PF6, are almost parallel [dihedral angle between planes =
2.4 (3)°]. The...
The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetrahydrofuran in the
presence of two equivalent...
The title compound, [Ni(C5H5)(C13H7N2)(C18H15P)] or (η5-C5H5)(PPh3)Ni—C[triple-bond]C—C7H6—C(H)=C(CN)2, contains an unusual disubstituted
norbornadienyl (NBD) ligand containing ...
